Thanks for your help guys, particularly Ed who is generally the greatest help of all
Pulled the head off yesterday after some very helpful advice from Mal Allen (MalFE).
First surprise was that it had no thermostat. Presumably this caused the water to flow through too quickly to cool the water but also was the reason it had always spat water out the overflow. Hard to know if the head gasket blew earlier or when it overheated on its last trip. Fairly academic now, it blew between 3 and 4, no apparent damage however I'm having the head crack tested as a precaution.
Lesson 1; Be more curious than I was when you think something isn't right, if I hadn't been so worried about breaking the nice shiny 2 pack engine paint I might have avoided this
Lesson 2; ALWAYS run a thermostat (and check it is working properly).....despite what the old(er) guys with pommy cars sometimes tell you...
Cheers
John